Journal
Organic Chemistry Frontiers
Volume 1, Issue 8, Pages 947-951Publisher
CHINESE CHEMICAL SOC
DOI: 10.1039/c4qo00132j
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Funding
- Wuhan University [203273463]
- 111 Project of the Ministry of Education of China
- National Natural Science Foundation of China [21372179]
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A new triphosphorus ligand, Tribi, was developed for the regioselective linear hydroformylation of terminal and internal olefins. It was shown to have excellent catalytic activity and regioselectivity. More importantly, the synthesis of the new triphosphorus ligand was scaled-up (>140 g scale) for practical industrial use. An effective method was also developed for the stepwise replacement of PPh3 by Tribi for potential industrial use.
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