4.2 Review

P-Acylphosphonium salts and their vinyloges - application in synthesis

Journal

CENTRAL EUROPEAN JOURNAL OF CHEMISTRY
Volume 8, Issue 6, Pages 1147-1171

Publisher

DE GRUYTER POLAND SP Z O O
DOI: 10.2478/s11532-010-0114-z

Keywords

Phosphine; Acylation; Enantioselective acylation; Isomerization of conjugated alkynes; Cycloaddition; Vinylphosphonium salts

Funding

  1. MSHE [N N204 228734]

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Review with 101 refs. of progress in synthetic applications and properties of P-acylphosphonium salts including acylation via P-acylphosphonium salts, enantioselective acylation using chiral phosphine ligands, nucleophilic (beta)-oniovinylation, and reaction involving vinyloges of P-acylphosphonium salts formed by treatment conjugated alkenoates or alkynoates with phosphines.

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