Journal
MATERIALS RESEARCH EXPRESS
Volume 1, Issue 1, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/1/1/015018
Keywords
II-VI semiconductors; micro-Raman spectroscopy; EXAFS spectroscopy; IR spectroscopy; ATM Green's function theory
Categories
Funding
- NTU Excellent Research Project [10R80908, 102R890954]
- School of Graduate Studies at Indiana University of Pennsylvania
- [NSC 98-2221-E-002-015-MY3]
Ask authors/readers for more resources
We have performed low-temperature micro-Raman scattering and extended x-ray absorption fine-structure (EXAFS) measurements on the Bridgman-grown bulk zinc-blende Cd1-xZnxTe (1.0 >= x >= 0.03) ternary alloys to comprehend their structural and lattice dynamical properties. The micro-Raman results are carefully appraised to authenticate the classical two-phonon mode behavior insinuated by far-infrared (FIR) reflectivity study. The composition-dependent EXAFS experiments have revealed a bimodal distribution of the nearest-neighbor bond lengths-its analysis by first-principles bond-orbital model enabled us to estimate the lattice relaxations around Zn/Cd atoms in CdTe/ZnTe to help evaluate the necessary force constant variations for constructing the impurity-perturbation matrices. The simulated results of impurity vibrational modes by average-t-matrix Green's function (ATM-GF) theory has put our experimental findings of the gap mode similar to 153 cm(-1) near x approximate to 1 on a much firmer ground.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available