Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 11, Pages 2763-2771Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qi00672e
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Funding
- NSFC [21533002, 21603075]
- China Ministry of Science and Technology [2016YFA0202804]
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The Sn-Beta zeolite is a unique solid Lewis acid catalyst, showing great potential in the Baeyer-Villiger oxidation reaction as well as the biomass conversion reactions. The direct hydrothermal synthesis of Sn-Beta often involved harmful F- ions when using tetraethylammonium hydroxide (TEAOH) as the structure-directing agent (SDA). In this study, N-cyclohexyl-N,N-dimethylcyclohexanaminium hydroxide was used as the SDA to synthesize the Sn-Beta zeolite in F--free medium. The combination of a small amount of Na+ ions and pure-silica Beta seeds proved to be critical for the successful synthesis of the highly crystalline Sn-Beta zeolite. The Si/Sn ratio could be tuned in the range of 60-200 by varying the gel Na/Si ratio. To obtain highly crystalline Sn-Beta zeolites, the removal of SDA molecules via calcination should be performed subsequent to NH4+ ion-exchange. With a smaller crystal size and stronger Lewis acidity, the obtained Sn-Beta showed a higher catalytic activity than that synthesized in F- medium with a comparable Sn content in both the Baeyer-Villiger oxidation reaction and isomerization-esterification reaction.
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