Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 2, Pages 119-123Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00276h
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Funding
- National Basic Research Program of China [2015CB856600]
- NSFC [21422206, 21272206, 21002087, J1210042]
- Fundamental Research Funds for the Central Universities [2014QNA3008]
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A copper(II)-catalyzed methoxylation of unactivated (hetero)aryl C-H bonds directed by our newly developed PIP directing group with methanol has been achieved. This protocol occurs efficiently with a catalytic amount of copper (5 mol%), is a simple and environmentally benign reaction system, has a broad substrate scope and high functional group tolerance.
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