Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 11, Pages 1511-1515Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00271k
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Funding
- 1000-Youth Talents Plan
- Sun Yat-sen University
- National Natural Science Foundation of China [81402794, 21472250]
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A mild and convenient oxidative radical cyclization of aryl alkynoate esters for the synthesis of 3-trifluoromethylthiolated and 3-thiocyanated coumarins has been developed using AgSCF3 and AgSCN as the corresponding radical sources, respectively. This protocol is characterized by readily available starting materials, excellent functional group tolerance and good yields.
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