Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 9, Pages 1080-1084Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00197h
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Funding
- 973 Program [2012CB821600]
- National Natural Science Foundation of China (NSFC)
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The combination of Pd(pi-allyl)Cp and PPh3 was found to generate an efficient catalyst for the formation of indole-containing alkyl iodides from ortho-amino iodobenzenes and both aromatic and aliphatic alkynes. A unique feature of this reaction is a palladium-promoted C(sp(3))-I bond formation via reductive elimination. This catalytic process was found to be very sensitive to the size and equivalents of phosphine ligands and the nature of the base.
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