Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 8, Pages 956-960Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00151j
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Funding
- NSFC [21232007]
- Ministry of Education
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Rh(II)/chiral phosphine combined catalysis has been developed for a highly efficient sequential C-H functionalization/asymmetric allylation or Michael addition reaction of indoles and 3-diazooxindoles with allenoates or vinyl ketones to afford a diverse range of quaternary 3,3'-indolyloxindole derivatives. Moreover, a significantly positive effect of LiCl in the sequential C-H functionalization/allylation reaction was observed, which led to an unusual ternary activation mechanism in the allylation step.
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