Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 3, Pages 226-230Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00336e
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Funding
- National Natural Science Foundation of China [21002089, 21372202]
- New Century Excellent Talents in University [NCET-12-1086]
- Zhejiang Natural Science Fund for Distinguished Young Scholars [R14B020005]
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Efficient and atom-economical access to indolizines has been developed by a Cu-catalyzed cyclization of 2-(2-enynyl)pyridines with various nucleophiles through simultaneous formation of a C-N bond and a remote carbon-nucleophile bond. 1,3-Dicarbonyl compounds, indoles, amides, alcohol, and even water, were used as nucleophiles in this reaction. Good to excellent yields of the corresponding indolizines were obtained under mild reaction conditions.
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