Journal
CHEMELECTROCHEM
Volume 5, Issue 21, Pages 3229-3235Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201800883
Keywords
sodium-ion batteries cathode; P2-type layered transition metal oxide; co-precipitation; sodium peroxide; high rate capability
Categories
Funding
- National Natural Science Foundation of China [21777108]
- Fundamental Research Funds for the Central Universities [20826041 A4031]
- Undergraduate Innovation and Entrepreneurship Training Program of Sichuan province [C2018101316]
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For the sake of achieving the practical application of sodium-ion batteries, extensive efforts have been made to improve the electrochemical performance of cathode materials. A simple co-precipitation route is successfully developed to synthesize nanowires of transition metal hydroxides through a sodium peroxide pouring process instead of the traditional sodium hydroxide dropping approach. After a subsequent annealing process, a well-crystallized P2-Na-0.56[Ni0.1Co0.1Mn0.8]O-2 layered cathode material is obtained. Owing to such an exquisite architecture, this material possesses an excellent electrochemical performance, exhibits a reversible capacity of 188 mAh g(-1) at 48 mA g(-1) in the voltage range of 1.5-4.1 V with nearly 99.7 % coulombic efficiency and retains approximately 80.2 % of the initial capacity after 50 cycles. Moreover, even at an extremely high current density of 2400 mA g(-1), it delivers a capacity of 134 mAh g(-1) and remains at 76 mAh g(-1) after 1500 cycles, which surpasses most reported layered transition metal oxide cathode materials. This strategy of providing a strong oxidizing environment during the co-precipitation process is especially crucial for obtaining materials with excellent electrochemical performances for future energy storage application.
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