Journal
CHEMELECTROCHEM
Volume 1, Issue 1, Pages 108-115Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201300053
Keywords
flexible cloth; heterojunctions; lithium-ion batteries; self-powered UV photodetectors; SnO2@TiO2
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Funding
- National Natural Science Foundation [21001046, 51002059]
- 973 Program of China [2011CB933300]
- Program for New Century Excellent Talents of the University in China [NCET-11-0179]
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To overcome the issue of inferior cycling stability and rate capacity for SnO2 anode materials in lithium-ion batteries, an effective strategy is explored to prepare a hybrid material consisting of rutile SnO2 nanoparticles and rutile TiO2 nanorods, considering not only the small lattice mismatch to achieve a better composited lattice structure but also their superior synergistic effect in electrochemical performances. The as-prepared SnO2@TiO2 material, directly formed on a carbon cloth as a binder-free anode, exhibits a reversible capacity of 700 mAhg(-1) after 100 discharge/charge cycles at 200 mAg(-1), as well as excellent cycling stability and rate capacity. After being calcinated at high temperature, the produced hollow SnO2@TiO2 hybrid microtubes were directly used to fabricate photoelectrochemical (PEC) UV detectors for future devices with self-powered function. A high photocurrent response of 0.1 mAcm(-2) was observed, together with an excellent self-powered and fast response and visible blind characteristics. Such a hybrid material could achieve a complementary effect in lithium-ion batteries and a superior band gap match in photovoltaic devices, and could consequently be extended to applications such as dye-sensitized solar cells and supercapacitors.
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