4.6 Article

Broadband Coherent Absorption in Chirped-Planar-Dielectric Cavities for 2D-Material-Based Photovoltaics and Photodetectors

Journal

ACS PHOTONICS
Volume 1, Issue 9, Pages 768-774

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ph500107b

Keywords

optimization; graphene; transition metal dichalcogenides; absorption enhancement; chirped distributed Bragg reflector

Funding

  1. Center for Re-Defining Photovoltaic Efficiency Through Molecule Scale Control, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001085]
  2. Empire State Development's Division of Science, Technology and Innovation (NYSTAR)
  3. New York State Energy Research Development Authority (NYSERDA)

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Atomically thin materials such as graphene and transition metal dichalcogenides are being developed for a range of optoelectronic devices, but their applications are currently limited by low light absorption. Here, we describe a dielectric cavity design with chirped Bragg reflectors for broadband coherent absorption. The chirped cavity absorption is calculated by the transfer matrix method and optimized using the Nelder-Mead optimization protocol. We numerically demonstrate that with cavity enhancement, a monolayer MoS2 photodetector absorbs as much as 33% of incident visible light over a 300 nm bandwidth, and the external quantum efficiency of an atomically thin monolayer graphene/monolayer MoS2 solar cell can be enhanced 3.6 times to a predicted value of 7.09%. The proposed layered dielectric structures operate across a wide range of incident angles and could enable applications for atomically thin photodetectors or solar cells.

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