Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 3, Pages 273-277Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qi00209a
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Funding
- Carbon Management Canada
- Alberta Innovates Technology Futures
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We report two porous Zr phosphonate frameworks. The kinetic product, ZrH2L-A, shows low order and is less porous. An HF-modulated structure, CALF-31, is more ordered and has higher porosity. While not single crystalline, CALF-31 is highly robust and the CO2 heats of adsorption give insights into ordering in phosphonate MOFs.
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