4.7 Article

Reconciling order, stability, and porosity in phosphonate metal-organic frameworks via HF-mediated synthesis

Journal

INORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 3, Pages 273-277

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qi00209a

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Funding

  1. Carbon Management Canada
  2. Alberta Innovates Technology Futures

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We report two porous Zr phosphonate frameworks. The kinetic product, ZrH2L-A, shows low order and is less porous. An HF-modulated structure, CALF-31, is more ordered and has higher porosity. While not single crystalline, CALF-31 is highly robust and the CO2 heats of adsorption give insights into ordering in phosphonate MOFs.

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