4.7 Article

Nickel hydroxide-nickel nanohybrids indirectly from coordination microfibers for high-performance supercapacitor electrodes

Journal

INORGANIC CHEMISTRY FRONTIERS
Volume 2, Issue 2, Pages 129-135

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qi00145a

Keywords

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Funding

  1. Program for New Century Excellent Talents of the University in China [NCET-13-0645]
  2. National Natural Science Foundation of China [NSFC-21201010, U1304504]
  3. Program for Innovative Research Team (in Science and Technology) in University of Henan Province [14IRTSTHN004]
  4. Science & Technology Foundation of Henan Province [122102210253, 13A150019]
  5. China Postdoctoral Science Foundation [2012M521115]

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Nickel nanowire foams are primarily synthesized by the calcination of dimethylglyoxime nickel microfibers in Ar gas. Moreover, mesoporous nickel hydroxide-nickel nanohybrids are successfully obtained via oxidation of Ni nanowire foams in an alkaline H2O2 aqueous solution. Due to the mesoporous structure of nickel hydroxide and the high conductivity of the central Ni metal, electrodes assembled with nickel hydroxide-nickel nanohybrids show a highly accessible surface-interface site and high conductivity, and are successfully applied as high-performance supercapacitor electrodes.

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