Journal
NANOSCALE RESEARCH LETTERS
Volume 9, Issue -, Pages -Publisher
SPRINGER
DOI: 10.1186/1556-276X-9-692
Keywords
Resistive switching; Al2O3; Cu pillar; 3D memory; CBRAM
Funding
- National Science Council (NSC) Taiwan [NSC-102-2221-E-182-057-MY2]
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Impact of the device size and thickness of Al2O3 film on the Cu pillars and resistive switching memory characteristics of the Al/Cu/Al2O3/TiN structures have been investigated for the first time. The memory device size and thickness of Al2O3 of 18 nm are observed by transmission electron microscope image. The 20-nm-thick Al2O3 films have been used for the Cu pillar formation (i.e., stronger Cu filaments) in the Al/Cu/Al2O3/TiN structures, which can be used for three-dimensional (3D) cross-point architecture as reported previously Nanoscale Res. Lett. 9: 366, 2014. Fifty randomly picked devices with sizes ranging from 8 x 8 to 0.4 x 0.4 mu m(2) have been measured. The 8-mu m devices show 100% yield of Cu pillars, whereas only 74% successful is observed for the 0.4-mu m devices, because smaller size devices have higher Joule heating effect and larger size devices show long read endurance of 10(5) cycles at a high read voltage of -1.5 V. On the other hand, the resistive switching memory characteristics of the 0.4-mu m devices with a 2-nm-thick Al2O3 film show superior as compared to those of both the larger device sizes and thicker (10 nm) Al2O3 film, owing to higher Cu diffusion rate for the larger size and thicker Al2O3 film. In consequence, higher device-to-device uniformity of 88% and lower average RESET current of approximately 328 mu A are observed for the 0.4-mu m devices with a 2-nm-thick Al2O3 film. Data retention capability of our memory device of >48 h makes it a promising one for future nanoscale nonvolatile application. This conductive bridging resistive random access memory (CBRAM) device is forming free at a current compliance (CC) of 30 mu A (even at a lowest CC of 0.1 mu A) and operation voltage of +/- 3 V at a high resistance ratio of >10(4).
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