Journal
NANOSCALE RESEARCH LETTERS
Volume 6, Issue -, Pages -Publisher
SPRINGEROPEN
DOI: 10.1186/1556-276X-6-484
Keywords
self-assembly; coordination polymer; catalysis; hydroxylation
Funding
- National Science Foundation of China [20871039]
- Anhui Provincial Science Research Projects [09020204030]
- University of Anhui Province [2011SQRL128]
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A feasible and effective self-assembly method to synthesize different scale coordination polymers in highly dilute solution (from nanocrystals to microcrystals and to bulk crystals) without any blocking agent has been described. The growth of crystalline particles was controlled by removing the particles at different reaction times to interrupt the growth at the desired size. The nano and microscale particles show better catalytic conversions and selectivities in the hydroxylation of phenols than the bulk crystals.
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