Cobalt phosphide nanorods as an efficient electrocatalyst for the hydrogen evolution reaction

Cobalt phosphide (CO2P) nanorods are found to exhibit efficient catalytic activity for the hydrogen evolution reaction (HER), with the overpotential required for the current density of 20 mA/cm(2) as small as 167 mV in acidic solution and 171 mV in basic solution. In addition, the Co2P nanorods can work stably in both acidic and basic solution during hydrogen production. This performance can be favorably compared to typical high efficient non-precious catalysts, and suggests the promising application potential of Co2P nanorods in the field of hydrogen production. The HER process follows a Volmer-Heyrovsky mechanism, and the rates of the discharge step and desorption step appear to be comparable during the HER process. The similarity of charged natures of Co and P in the Co2P nanorods to those of the hydride-acceptor and proton-acceptor in highly efficient Ni2P catalysts, [NiFe] hydrogenase, and its analogues implies that the HER catalytic activity of the Co2P nanorods might be correlated with the charged natures of Co and P. (C) 2014 Elsevier Ltd. All rights reserved.