Journal
NANO ENERGY
Volume 10, Issue -, Pages 229-234Publisher
ELSEVIER
DOI: 10.1016/j.nanoen.2014.07.026
Keywords
Hierarchical nanoarrays; Aqueous battery; Energy density; Power density
Categories
Funding
- National Natural Science Foundation of China
- 973 Program [2011CBA00503, 2011CB932403]
- Program for New Century Excellent Talents in Universities
- Program for Changjiang Scholars and Innovative Research Team in University
Ask authors/readers for more resources
Considerable efforts have been devoted to pursue both higher energy density and power density for a number of energy storage devices. Here we report a hierarchical CoxFe3-xO4 nanoarray which is directly grown on three-dimensional conductive substrates by a facile two-step hydrothermal reaction and a following annealing treatment. This hierarchical structure provides several advantages including a large contact surface area, short ion diffusion path and good charge transport, which are all beneficial for improving the electrochemical performance. As an integrated anode electrode in aqueous electrolyte, it delivers a high discharge capacity of similar to 2.13 mAh cm(-2) (or similar to 304.30 mAh g(-1)) at a scan rate of 1 mV s(-1), retains at similar to 1.68 mAh cm(-2) at 10 mV s(-1), and preserves similar to 88% of the initial capacity after 500 cycles. Combining our hierarchical Co3O4@Ni-Co-O nanoarray as the cathode electrode, we assemble a double hierarchical structured aqueous battery, which achieves an energy density and power density of similar to 2.1 mWh cm(-2) and 42.8 mW cm(-2), respectively. It also exhibits good cycling stability with a capacity of similar to 1.8 mAh cm(-2) after 500 charge/discharge cycles. (C) 2014 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available