4.6 Article

Insight into chirality on molecular stacking for tunable ultralong organic phosphorescence

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 6, Issue 38, Pages 10179-10183

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc03297a

Keywords

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Funding

  1. National Natural Science Foundation of China [51673095, 21875104, 61505078]
  2. National Basic Research Program of China (973 Program) [2015CB932200]
  3. Natural Science Foundation [BK20150064]
  4. Natural Science Fund for Colleges and Universities [17KJB430020]
  5. Nanjing Tech Start-up Grant [3983500158, 3983500169]
  6. High-Level Talents in Six Industries'' of Jiangsu Province [XCL-025]

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A new levorotatory compound ((S)-9,9'-(6-(1-phenylethoxy)-1,3,5-triazine-2,4-diyl)bis(9H-carbazole)) and its corresponding racemic compound show different intermolecular interactions to restrain nonradiative transition, resulting in an enhanced ultralong organic phosphorescence lifetime from 229.0 ms to 419.8 ms. This work will provide a new insight into the chirality of organic molecules to adjust the ultralong phosphorescence.

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