Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 2, Issue 42, Pages 9028-9034Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4tc01680g
Keywords
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Funding
- NSF of China [51173092, 51073083, 51303091]
- NSF of Qingdao City [13-1-4-207-jch]
- Specialized Research Fund for the Doctoral Program of Higher Education [20133371912 0005]
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In this work, we have synthesized a tetradonor-capped anthracene-centered cruciform 2,6,9,10-tetra(p-dibutylaminostyryl)anthracene (TDC) and its optical properties are investigated. TDC is a light- and heat-stable dye and shows aggregation-enhanced emission (AEE), large and enhanced two-photon absorption cross sections (delta), fluorescence sensing selectively to transition metal ions such as Zn2+ and Cu2+, and appreciable piezofluorochromism (PFC), which is rarely found to exist simultaneously in cruciform or other configuration dyes. The AEE and PFC behaviours result from the existence of a strongly twisted 9,10-branch, and the large and enhanced delta is ascribed to the multiple conjugation pathways and introduction of donor end-groups. TDC possesses a non-centrosymmetric structure and a semi-disjoint Frontier molecular orbital, which could rationalize its fluorescence sensing selectively to Zn2+ and Cu2+. These findings indicate further that an anthracene ring is indeed a unique pi-center that is different from other pi-centers and can construct novel cruciforms with interesting optical properties.
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