Solution-processed, indacenodithiophene-based, small-molecule organic field-effect transistors and solar cells

Two indacenodithiophene-based molecules with different side chains, BTIDT-C6 and BTIDT-OC12, have been designed and synthesized for solution-processed, small-molecule organic solar cells (OSCs) donor materials. By optimizing the side chains, the hole mobility of the materials is modulated, which has been proven by the organic field-effect transistor (OFET) performances. Solar cells based on BTIDT-C6 show a power conversion efficiency (PCE) of 4.83%. To the best of our knowledge, this is the first report about indacenodithiophene-based, solution-processed, small-molecule OFETs, and it is also one of the highest PCE reports for the indacenodithiophene-based, solution-processed, small-molecule OSCs. This report makes indacenodithiophene-based small molecules the third type of high-efficiency (5% PCE), solution-processed, small-molecule OSCs donor materials, in addition to benzodithiophene (BDT) and dithienosilole (DTS).