Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 34, Pages 16465-16474Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta06160b
Keywords
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Funding
- National Natural Science Fund of China [21601108]
- Fundamental Research Funds of Shandong University [2016JC033, 2016GN010]
- Taishan Scholar Project of Shandong Province [ts201511004]
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Hard carbon has been identified as a promising anode material for sodium-ion batteries (SIBs). Herein, a facile self-templating strategy has been developed for the kilogram-scale preparation of N,O-codoped hierarchical porous hard carbon cuttlefish-like nanowire bundles (denoted as NOHPHC cuttlefishes). The unique nanoarchitecture leads to ultrafast pseudocapacitive sodium storage, excellent reversibility, and negligible degradation of the host material. NOHPHC delivers a high reversible capacity of 184 mA h g(-1) at 0.5 A g(-1), which is maintained at 114 mA h g(-1) at 5 A g(-1) for over 30000 cycles, as well as exceptional rate capability of up to 20 A g(-1) with a capacity of approximately 100 mA h g(-1). Importantly, samples prepared before and after kilogram scaling are comparable in performance. Coupled with a Na3V2(PO4)(3)/C cathode, a full cell successfully obtains a high energy density of 52.6 W h kg(-1) at 50 W kg(-1) and 34 W h kg(-1) at 1.4 kW kg(-1).
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