Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 48, Pages 20450-20453Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta04396k
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Funding
- 973 program [2012CB821702]
- NSFC [21331003]
- MOE [20120031130001, IRT13022, 13R30]
- 111 project [B12015]
- NSF of Tianjin [13JCZDJC32200]
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Two novel isostructural 3d-4f microporous heterometal-organic frameworks (HMOFs) with high acid/base stability were constructed based on a polydentate carboxylate ligand. Luminescent studies showed that one of the new HMOFs displayed high-sensitivity luminescent sensing functions for BTEX (benzene, toluene, ethylbenzene, xylenes), particularly for ethylbenzene. This is the first observation of a 3d-4f HMOF as a chemical sensor for BTEX.
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