4.6 Article

A high molecular weight triisopropylsilylethynyl (TIPS)-benzodithiophene and diketopyrrolopyrrole-based copolymer for high performance organic photovoltaic cells

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 18, Pages 6348-6352

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta00535j

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Funding

  1. Center for Advanced Soft Electronics under Ministry of Education, Science and Technology, Korea [2012055225]
  2. NRF [20110016177]
  3. Korea government (MSIP) through GCRC-SOP [2011-0030013]
  4. MEST

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A high-molecular-weight conjugated polymer consisting of alternating TIPS-substituted benzo[1,2-b: 4,5-b'] dithiophene (BDT) and diketopyrrolo[3,4-c] pyrrole (DPP) was synthesized by Suzuki cross-coupling and characterized for use in high performance OPVs. Good structural order, self-assembly in spun-cast films, and carrier mobility were observed. PTIPSBDT-DPP showed an OFET hole mobility of up to 0.12 cm(2) V-1 s(-1). Power conversion efficiencies of up to 8.0% were demonstrated for OPV devices.

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