4.6 Article

Nitrogen-doped hollow carbon hemispheres as efficient metal-free electrocatalysts for oxygen reduction reaction in alkaline medium

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 3, Pages 605-609

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta13757k

Keywords

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Funding

  1. National Natural Science Foundation of China [U1162124, 21376208]
  2. Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars of China [LR13B030001]
  3. Specialized Research Fund for the Doctoral Program of Higher Education [J20130060]
  4. Fundamental Research Funds for the Central Universities
  5. Program for Zhejiang Leading Team of ST Innovation
  6. Partner Group Program of the Zhejiang University
  7. Max-Planck Society

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Honeycomb-like N-doped hollow carbon hemispheres are synthesized by a facile and versatile process, using ionic liquids as the carbon source. The resulting materials show a unique hollow hemisphere morphology, outstanding electrochemical activity, strong immunity towards methanol crossover and stability superior to the commercial Pt/C catalyst in alkaline medium.

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