Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 33, Pages 13534-13540Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta01364f
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Funding
- NUS
- POC grant from National Research Foundation of Singapore
- Singapore Ministry of Education
- National Natural Science Foundation of China [21233006]
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A cross-linked organo-magnesium complex (MTF-Mg) was synthesized and investigated for selective CO2 adsorption over N-2 at 298 K. Remarkably high selectivity and reversibility were achieved with an isosteric heat of adsorption of 45.2 kJ mol(-1) for CO2, consistent with the predicted DFT value of 37.3 kJ mol(-1). The CO2 preferential adsorption arises from its strong interaction with the exposed magnesium atoms.
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