Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 13, Pages 4676-4681Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta14429a
Keywords
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Funding
- National Program on Key Basic Research Project of China (973 Program) [MOST2011CB935700]
- National Natural Science Foundation [21202178, 21271180]
- Shandong Province Natural Science Foundation [ZR2011BQ024, ZR2013FZ001, ZR2010BM016]
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Hierarchical nanocomposites of iron carbide (Fe3C) encaged in nitrogen-doped carbon (N-C) were prepared by using a simple carbothermal reduction of iron(II) oxalate (FeC2O4) nanowires in the presence of cyanamide (NH2CN) at 600 degrees C. Such Fe3C@N-C nanocomposites delivered fair electrocatalytic activity for the I3(-)/I- redox reaction. As a result, when explored as cost-effective counter electrodes of dye-sensitized solar cells, an efficiency of 7.36% was achieved, which was comparable to that of the cell with a Pt-FTO counter electrode (7.15%) under the same experimental conditions. The good electrochemical performance is attributed to the synergistic effect of the combination of N-C and Fe3C and the one dimensional configuration, which endows the nanocomposites with more interfacial active sites and improved electron transfer efficiency for the reduction of I3(-)/I-
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