Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 26, Pages 10034-10040Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta00316k
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Funding
- Belgian Government (IAP-PAI networking)
- Flemish Government (Methusalem (CASAS))
- Flemish Government (FWO) [G069811]
- KU Leuven [IOF-KP/10/002, OT 11/061]
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Metal-organic frameworks (MOFs) are an emerging class of materials for potential use in separation. ZIF-71 has super-hydrophobic pore channels and a very flexible pore architecture, which make ZIF-71 a potential candidate for recovering bio-alcohols from fermentation broths. In the present study, mixed matrix membranes (MMMs) based on PDMS and ZIF-71 were prepared for separation of alcohols (methanol, ethanol, isopropanol (IPA) or sec-butanol) from aqueous solutions. Experimental results reveal that the pervaporation performance of the PDMS membrane was improved in both flux and separation factors upon embedment of ZIF-71. The pervaporation separation factors for alcohols of ZIF-71 filled the PDMS membrane (PDMS : ZIF-71 = 10 : 2) nearly double compared to those of unfilled PDMS membranes, suggesting that ZIF-71 is an excellent filler to prepare organophilic pervaporation membranes for bio-alcohol recovery.
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