Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 3, Pages 581-584Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta13691d
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Funding
- U.S. Department of Energy's Office of Basic Energy Science, Division of Materials Sciences and Engineering
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A unique class of air-stable and non-pyrophoric magnesium electrolytes has been developed based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg3Cl3(OR)(2)(THF)(6)](+) [(THF)MgCl3](-). High reversible capacities and good rate capabilities have been obtained in Mg-Mo6S8 batteries using these new electrolytes at both 20 and 50 degrees C.
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