4.6 Article

Electronic structural insights into efficient MnOx catalysts

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 43, Pages 18199-18203

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta04185b

Keywords

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Funding

  1. Helmholtz-Gemeinschaft [VH-NG-635]
  2. European Research Council [279344]
  3. Higher Education Commission of Pakistan
  4. Deutscher Akademischer Austauschdienst
  5. Alexander von Humboldt Foundation
  6. Australian Research Council through the Australian Centre of Excellence for Electromaterials Science
  7. European Research Council (ERC) [279344] Funding Source: European Research Council (ERC)

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Soft X-ray absorption and resonant inelastic X-ray scattering at the Mn L-edge are established as tools for gaining electronic structural insights into water oxidation catalysis. The MnOx catalyst with the lowest d-d transitions, strongest charge transfer and a higher proportion of Mn3+ over Mn2+/4+ produces itinerant electrons that contribute to a higher catalytic activity.

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