Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 24, Pages 9011-9014Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta01408a
Keywords
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Funding
- National Natural Science Foundation of China [U1205112, 21301060, 61306077]
- Chinese Ministry of Education [211204]
- Promotion Program for Young and Middle-aged Teacher in Science and Technology Research of Huaqiao University [ZQN-PY106]
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A redox-active gel polymer electrolyte was prepared by introducing KI/VOSO4 redox additives into a polyvinyl alcohol-H2SO4 gel electrolyte for application in a quasi-solid-state electric double-layer capacitor (EDLC) based on activated carbon. The EDLC obtained had a high electrode-specific capacitance of 1232.8 F g(-1) and a high energy density of 25.4W h kg(-1); these values are higher than that of an EDLC with a conventional gel electrolyte. The improved energy storage is attributed to Faradaic pseudocapacitance related to the redox-active ions in the gel polymer electrolyte.
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