4.6 Article

Metal-organic frameworks: a new promising class of materials for a high performance supercapacitor electrode

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 39, Pages 16640-16644

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta04140b

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Funding

  1. National Natural Science Foundation of China [NSFC 21173049, J1103303]
  2. Research Fund for the Doctoral Program of Higher Education of China [RFDP 20133514110002]

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A layered structure Ni-based MOF was synthesized and, for the first time, was used as the electrode material for a supercapacitor. It exhibited large specific capacitance, high rate capability and cycling stability. Capacitances of 1127 and 668 F g(-1) can be achieved at rates of 0.5 and 10 A g(-1), respectively. At the same time, over 90% performance was retained after 3000 cycles. These excellent electrochemical properties may be related to the intrinsic characteristics of Ni-based MOF materials.

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