Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 5, Pages 1239-1241Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta14058j
Keywords
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Funding
- NSF CAREER award (CBET) [1054 150]
- National Energy Technology Laboratory's Regional University Alliance (NETL-RUA), a collaborative initiative of the NETL [DE-FE0004000]
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1054150] Funding Source: National Science Foundation
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1449852] Funding Source: National Science Foundation
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The synthesis of continuous cobalt-adeninate MOF (bio-MOF-13 (I) and bio-MOF-14 (II)) membranes supported on porous alumina tubes is demonstrated. The membranes showed high CO2 permeabilities and low to moderate CO2 separation selectivities for CO2/CH4 gas mixtures. The observed CO2/CH4 selectivities are attributed to preferential CO2 adsorption within the framework.
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