4.6 Article

A ZnO nanorod/nanoparticle hierarchical structure synthesized through a facile in situ method for dye-sensitized solar cells

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 13, Pages 4765-4770

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta15276f

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Funding

  1. US Department of Energy, Office of Basic Energy Sciences, Division of Materials and Engineering [DE-FG02-07ER46467]
  2. National Science Foundation [DMR-1035196]
  3. National Natural Science Foundation of China [51273104]
  4. National Key Basic Research and Development Program of China [2009CB930602]

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A novel ZnO nanorod/nanoparticle (NR/NP) hierarchical structure on a zinc foil has been fabricated through a chemical bath deposition method. When used as a flexible photoanode for DSSCs, such a structure demonstrated enhanced dye-loading and electron lifetime as compared to the NR structure. It also retarded the charge recombination while maintaining the electron diffusion length of the NR structure. As a result, the power conversion efficiency of the DSSCs based on the NR/NP structure increased from 1.35% to 3.63% with a 169% enhancement as compared to that based on ZnO NRs.

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