Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 2, Pages 303-307Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta14132b
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Funding
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-FG02-07ER15907]
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The solution phase n-doping of C-60 and PCBM with tetrabutylammonium fluoride is shown to occur via an initial chemical reaction followed by electron transfer to a second fullerene molecule. The formation of ionic and radical intermediate species has significant implications for the use of ionically functionalized materials as electron-selective interface layers in OPVs.
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