Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 5, Pages 1235-1238Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta13792a
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Funding
- Alexander von Humboldt Foundation
- EU CARENA [FP7-NMP-2010-LARGE-4, 263007]
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This study demonstrates that the interlayer galleries of layered compounds can exhibit size selectivity. A compact NiAl-CO3 layered double hydroxide membrane was prepared showing a selectivity of similar to 80 for the H-2-CH4 mixture. The use of the gamma-Al2O3 modified alpha-Al2O3 substrate and CO2-saturated water solvent was essential for high-quality membrane fabrication.
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