Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 37, Pages 15463-15472Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta02920h
Keywords
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Funding
- Foundation of Furong Scholar project of Hunan Province
- honorary professorship
- National Natural Science Foundation of China [41301338]
- Hunan Provincial Natural Science Foundation of China [13JJ4069]
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Alginate microcapsules immobilized nanoscale zero-valent iron (M-NZVI), with diameters from several hundreds nanometers to several micrometers, were synthesized using ferric and calcium ions as the cross-linking cations, and then tested for removal of Pb(II) from aqueous solution. The size of NZVI particles was only a few nanometers according to transmission electron microscopy (TEM) observation. The synthesized alginate microcapsules were stable in air for as long as they were dried and contained 9.97% of iron by weight. When 0.5 g L-1 of M-NZVI were introduced into an aqueous solution containing 300.0 mg L-1 of Pb(II), 88% of Pb(II), 581.7 mg g(-1) of Pb(II) uptake amount were removed from the system in 15 min. The kinetics of the removal reactions, including an initial adsorption phase and a subsequent reduction, is complicated. In addition, the synthesized M-NZVI showed a higher removal capability of Pb compared to NZVI and Ca-alginate particles. This newly synthesized material could be regenerated and reused at least 4 times when the initial concentrations of Pb(II) were <= 200.0 mg L-1. The higher reaction rates and greater removal capacity suggest that M-NZVI may be a potential material for in situ remediation of metal contaminated water and sediments.
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