Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 32, Pages 12918-12923Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta02021a
Keywords
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Funding
- National Natural Science Foundation of China [50974045]
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Three-dimensional porous Sn-graphene composites have been prepared on Ni foam by an easy, binder-free, low-cost and ultrafast electrophoretic deposition method. The structure and morphology of the as-prepared composite material are characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, high resolution transmission electron microscopy, field emission scanning electron microscopy and elemental analysis. The lithium storage performance of the three-dimensional porous Sn-graphene anode is evaluated by cyclic voltammetry, galvanostatic charge-discharge cycling, and electrochemical impedance spectroscopy measurements. Results show that the composite material with a graphene content of 6.1 wt% delivers a reversible capacity of 552 mA h g(-1) after 200 cycles at a current density of 500 mA g(-1). The synthetic approach presented in this work may provide a facile strategy for the preparation of three-dimensional porous metal-graphene composites.
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