Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 29, Pages 11426-11431Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta00531g
Keywords
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Funding
- Global Frontier R&D Program of the Center for Multiscale Energy Systems - National Research Foundation under the Ministry of Science, ICT Future, Korea [2011-0031561]
- Human Resources Development Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Korean government's Ministry of Knowledge Economy [20124010203170]
- Deutsche Forschungsgemeinschaft (DFG) [IRTG 1404]
- BK21 Plus program
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We have investigated the photovoltaic properties of inverted solar cells comprising a bulk heterojunction film of thieno[3,4-b]-thiophene/benzodithiophene (PTB7) and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM), sandwiched between indium tin oxide (ITO)/Sn-doped TiO2 front and MoO3/aluminum back electrodes. The inverted organic solar cell (IOSC) fabricated with a Sn-doped TiO2 film showed a significantly greater power conversion efficiency of 7.59%, compared to that of the TiO2 film (6.70%). Further studies confirm that the improved morphology and electrical properties of the Sn-doped TiO2 film result in reduced shunt loss and interfacial charge recombination and hence enhanced photovoltaic performance.
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