4.6 Article

A Na4Fe(CN)6/NaCl solid solution cathode material with an enhanced electrochemical performance for sodium ion batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 43, Pages 13417-13421

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta12994b

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Funding

  1. Natural Science Foundation of China [21073120, 21006063, 21336003]
  2. 973 program of China [2014CB239700]

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A Na4Fe(CN)(6)/NaCl solid solution was synthesized and investigated as a cathode material for sodium ion batteries. Pure Na4Fe(CN)(6) and NaCl do not work as cathode materials for sodium ion batteries, while a sample of Na4Fe(CN)(6)/NaCl demonstrated a remarkably enhanced Na+ insertion/extraction capability and electrochemical performance, due to the cation vacancies and interconnected cages generated in the solid solution framework.

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