Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 4, Pages 1261-1269Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ta00545j
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Funding
- Wuhan University [121075]
- NSFC [21203141]
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For the first time, a mesoporous hexagonal-phase Na0.17WO3.085.0.29H(2)O nanosheet/microflower hierarchical structure has been synthesized employing a one-pot hydrothermal process with the assistance of Na2SO4. It is shown that Na2SO4 not only acts as a stabilizer to facilitate the generation of a metastable hexagonal phase, but also function as a structure directing agent to assist the construction of nanosheet assemblies. The formation mechanisms have been rationalized. The materials have been thoroughly characterized by XRD/BET/FESEM/EDX/TEM/TGA. This hexagonal-phase Na0.17WO3.085.0.29H(2)O nanosheet/microflower hierarchical structure exhibits applicable electrochromic and adsorptive properties due to its unique crystallographic configuration and microstructures, promising its application in energy-saving smart windows and wastewater treatment.
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