Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 46, Pages 14455-14459Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta13190d
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Funding
- Nanyang Technological University, Singapore
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PVDF-g-HEMA [poly(vinylidene fluoride)-graft-poly(2-hydroxyethylmethacrylate)]/Barium Titanate (BaTiO3) nanocomposites were prepared successfully via an in situ synthesis method without any catalyst or initiator. The in situ synthesis approach enables the formation of oxide nanoparticles in the presence of the grafted polymer with a hydroxyl functionalization group for direct coupling with oxide nanofillers. This elegant in situ nanoparticle synthesis method provides a facile, cost-effective and void-free dispersion of the nanoparticles in thematrix. The dielectric nanoparticle (BaTiO3) is well-attached onto the insulating polymer (PVDF) surface due to the surface anchoring linkage through hydrogen bonding between the two components, leading to the reduced aggregation in the resultant nanocomposites. The novel PVDF-g-HEMA/BaTiO3 nanocomposites are investigated as high energy density capacitormaterials, achieving highest dielectric constant reaching up to 333, and a dielectric loss of 0.73 at 30 wt% BaTiO3 at 1 kHz.
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