Unique hydrogenated Ni/NiO core/shell 1D nanoheterostructures with superior electrochemical performance as supercapacitors

This study demonstrates a scheme to design and fabricate a novel 1D core/shell Ni/NiO nano-architecture electrode as a pseudocapacitor with significantly improved capacitive performance through hydrogenation. The specific capacitance of the as prepared 1D core/shell Ni/NiO nanoheterostructure (717 F g(-1) at a scan rate of 2 mV s(-1)) is nearly 1635 F g(-1) after the hydrogenation. The improved pseudocapacitive properties of hydrogenated Ni/NiO nano-heterostructures are attributed to the incorporation of the hydroxyl groups on the NiO surface due to hydrogenation, where the metallic Ni nanowire core of this unique 1D core/shell heterostructure serves as the efficient channel for the fast electron conduction to the current collector. The H-Ni/NiO nanoheterostructures exhibit good rate capability (retaining nearly 60% of their initial charge) and good long-term cycling stability with an excellent specific energy and power density of 49.35 W h kg(-1) and 7.9 kW kg(-1), respectively, at a current density of 15.1 A g(-1). This study demonstrates that the H-Ni/NiO nano-heterostructure is very promising for next generation high-performance pseudocapacitors.