Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 18, Pages 5497-5500Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta10766c
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Funding
- EPSRC [EP/H046305/1]
- Engineering and Physical Sciences Research Council [EP/H046305/1, EP/F020546/1] Funding Source: researchfish
- EPSRC [EP/F020546/1] Funding Source: UKRI
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A facile polyethylenimine (PEI)-assisted dip-coating method allows crack-free films of MIL-101(Cr) and MIL-101(Cr)-NH2 to be prepared on alumina supports. The presence of PEI enhances the selectivity of the films for CO2 with respect to N-2. The film surfaces can be made hydrophobic by further dip-coating with an aliphatic monocarboxylic acid.
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