Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 1, Pages 122-127Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ta00223j
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Novel nano-heterostructures composed of Fe2O3 hollow nanorods on both the outer and inner surface of the aligned TiO2 nanotube arrays (TNAs) have been fabricated by growing FeOOH nanospindles onto the TNAs, and then followed by thermal transformation in air. Owing to their structural advantages, such a hierarchical architecture exhibits superior electrochemical performance with a remarkable areal capacity of over 600 mu A h cm(-2) at a current density of 100 mu A cm(-2) for 50 cycles(similar to 680 mu A h cm(-2) at 100 mu A cm(-2)). This hierarchal structure might be easily integrated as a binder-free electrode for microscale lithium-ion batteries considering the improved performance and the simple synthesis.
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