Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 43, Pages 13454-13461Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta13303f
Keywords
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Funding
- National Natural Science Foundation of China [51001089, 51271169]
- Key Science and Technology Innovation Team of Zhejiang Province [2010R50013]
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A versatile ionothermal strategy is proposed to synthesize nanostructured nickel compounds as energy storage materials, such as Ni(NH3)(6)Cl-2 crystals, nanosheet-like NiCl2, nanoflower-like (NF) alpha-Ni(OH)(2), and mesoporous NF-NiO. The primal solution is a choline chloride (ChCl)-urea mixture-based ionic liquid with nickel chloride hexahydrate (NiCl2 center dot 6H(2)O) dissolved. The proposed ionothermal protocol is attractive and environmental friendly because ChCl and urea are naturally biocompatible compounds. It has been reported that Ni(NH3)(6)Cl-2 is an indirect and reversible hydrogen storage material for fuel cells. Herein, we demonstrate that Ni(NH3)(6)Cl-2 crystals with octahedral geometry and an open structure can be obtained by maintaining the primal solution in a sealed vessel at 150 degrees C for 4 hours. A kinetic-to-dynamic growth mechanism is proposed to elucidate the formation of the interesting Ni(NH3)(6)Cl-2 structure. Further annealing of the Ni(NH3)(6)Cl-2 crystals at 300 degrees C produces sheet-like NiCl2, which can be utilized as an active material in sodium-ion batteries. Interestingly, with the addition of a small amount of water into the primal solution which has been kept at 150 degrees C and open to the air for 40 minutes, NF alpha-Ni(OH)(2) can be obtained. Further annealing of the NF alpha-Ni(OH)(2) at 300 degrees C leads to the formation of NF-NiO with a mesoporous structure, which is demonstrated to be a promising pseudo-capacitive electrode material in a KOH aqueous solution. The rapid activation process, good cycling performance, and high specific capacitance of the NF-NiO electrode are attributed to its high surface area (72.9 m(2) g(-1)) and the mesoporous structure. We expect that the ionothermal method will have implications for the use of ChCl-urea mixture-based ionic liquids in the large-scale synthesis of advanced functional materials.
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