Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 22, Pages 6550-6552Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta10878c
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- JSPS
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A new zero-strain system, spinel Li1+xRh2O4, is found as an insertion material for lithium ions. A very small volume change of ca. 0.5% is observed in the two-phase reaction process. The zero-strain behavior is likely induced by itinerant t(2g) electrons with a suppressed Jahn-Teller effect.
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