4.6 Article

Dynamic Zn-based metal-organic framework: stepwise adsorption, hysteretic desorption and selective carbon dioxide uptake

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 22, Pages 6535-6538

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta10918f

Keywords

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Funding

  1. NSF of China [20771090, 20931005, 91022004]
  2. Doctoral Program of Higher Education of China [20096101110005]
  3. NSF of Shaanxi, China [2009JZ001]

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A new porous metal-organic framework based on paddle-wheel Zn-2 units and an unsymmetrical pyridyl dicarboxylate, contains a 3D intersecting pore system with uncommon stepwise adsorption and hysteretic desorption behavior for N-2, CO2 and H-2 gases at low temperature, and shows high selectivity for CO2 over N-2 at ambient temperature.

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