4.6 Article

A novel nitrogen rich porous aromatic framework for hydrogen and carbon dioxide storage

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 44, Pages 13800-13806

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta13194g

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Funding

  1. US Department of Energy [DE-FG36-04G014224]
  2. Florida Hydrogen Initiative (DOE-FHI) [20126050]

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A nitrogen rich, p-phenylenediamine based, porous aromatic framework (NPAF) with 1790 m(2) g(-1) BET surface area has been synthesized by using a Yamamoto coupling technique. The NPAF has shown a hydrogen uptake of 1.87 and 0.33 wt% at 77 K per 1 atm and 298 K per 80 bar, respectively. The CO2 uptake and selectivity of the NPAF at 273 K per 1 atm is 3.64 mmol g(-1) and 48, respectively.

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