Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 1, Issue 3, Pages 495-499Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ta00635a
Keywords
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Funding
- 973 Program of China [2007CB815305]
- NNSF of China [21031002, 20801029]
- Natural Science Fund of Tianjin, China [10JCZDJC22100]
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Two cluster-based microporous MOFs containing coordination unsaturated metal(II) sites (or open metal(II) sites) have been constructed from boxlike or cagelike {M3}(x) SBUs. They both exhibit highly selective uptake for CO2 over CH4 and N-2 under ambient conditions. More importantly, MOF-1 also provides an ideal luminescence sensor for selective probing Ba2+ and Cu2+ ions based on significant luminescence enhancement or quenching.
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